UNIVERSITY OF BUCHAREST
FACULTY OF PHYSICS

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2024-11-23 14:55

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Conference: Bucharest University Faculty of Physics 2008 Meeting


Section: Polymer Physics


Title:
Nanoscale Alignment and Optical Nanoimaging of a Liquid Crystal


Authors:
Valentin Barna(1),Antonio De Luca(2), Charles Rosenblatt(3)


Affiliation:
(1)Faculty of Physics, University of Bucharest, Romania, 70709, Bucharest, Romania;

(2)LICRYL (INFM-CNR) and Center of Excellence CEMIF.CAL, Department of Physics, University of Calabria, I-87036 Rende (CS), Italy;

(3)Department of Physics, CWRU University, Cleveland, Ohio, 44106, USA.


E-mail
barnavalentin@yahoo.com


Keywords:
Nanopatterning, Polymeric Materials, Optical Nanotomograpy, Liquid Crystals.


Abstract:
An anisotropic nanopatterning method, based on an atomic force microscopy (AFM) scribing technique of a thin polyimide film, is used to generate an alignment layer whose topography depends on the writing direction. Detailed experimental measurements are presented for the topographical anisotropy that arises when the polyimide alignment layer is scribed parallel and antiparallel to the AFM cantilever orientation. By means of a novel nanotomographic approach, the optical retardation δ of an alignable birefringent liquid that covers the scribed substrate is measured with unprecedented resolution of only a few tens of nanometers. In this technique a thin optical fiber is raster-scanned at several fixed heights inside the birefringent liquid, and the transmitted polarized light is collected downstream. The optical retardation δ from the fiber`s tip to the polyimide interface was measured as a function of position x,y,z, with the results reflecting the spatially-varying depth of the medium due to the polymer film surface topography. Theoretical calculations for δ are in excellent agreement with both the obtained topographical and the high resolution nanoimaging experimental results.