UNIVERSITY OF BUCHAREST
FACULTY OF PHYSICS

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2024-11-22 1:46

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Conference: Bucharest University Faculty of Physics 2015 Meeting


Section: Physics and Technology of Renewable and Alternative Energy Sources


Title:
Recovering hydrogen sulfide from sulfurous waters with pem-fuel cells


Authors:
Ștefan.M. IORDACHE(1), Adrian CIOCĂNEA(2), Adriana BĂLAN(1), Ioan STAMATIN(1), Șerban N. STAMATIN(1), Sanda BUDEA(2), Ana-Maria IORDACHE(1), Cătălin CEAUȘ(1), Ana CUCU(1), Laurențiu POPOVICI(1), Sanda VOINEA(1)


Affiliation:
1)University of Bucharest, Faculty of Physics, 3Nano-SAE Research Centre, PO Box MG-38, Bucharest-Magurele, Romania

2)Politehnica University of Bucharest, Faculty of Power Engineering, 313 Independentei Spl., 060042 Bucharest, Romania


E-mail
sandavoinea@3nanosae.org


Keywords:
fuel cells, hydrogen sulfide, wastewater treatment, sulfur recovering


Abstract:
Hydrogen sulfide is an environmental pollutant and abundant in various sulfurous waters such as Black Sea. Hydrogen sulfide is in the same time a potential energetic materials as source for hydrogen production. In this respect, designing an appropriate fuel cell with proton exchange membranes (PEMFC) for hydrogen sulfide recovering from sulfurous water is challenge. This study reports a PEMFC with Pt/Pt-Ru catalysts and membrane with perflurosulfonic ionomer. PEMFC was calibrated using a couple methanol-water/ air and further to water with 1 mg/l hydrogen sulfide concentration. Even though power density and current density are then times lower than methanol-water the FC with hydrogen sulfide show a promising perspective for sulfurous water treatment.


Acknowledgement:
Authors acknowledge research support provided under Grant, IDEI ctr 64 IDEI PN-II-ID-PCE-2011-3-0815 (UEFISCDI).