UNIVERSITY OF BUCHAREST
FACULTY OF PHYSICS

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Conference: Bucharest University Faculty of Physics 2015 Meeting


Section: Physics and Technology of Renewable and Alternative Energy Sources


Title:
Advanced Ni catalysts for Urea Fuel Cells applications


Authors:
Cristina E. SERBAN(1), Adriana E. BALAN(1), Alexandra M. I. TREFILOV(1), Mihaela NECULA(2), Sonia MIHAI(2), Diana L. CURSARU(2), Ioan STAMATIN(1)


Affiliation:
1)University of Bucharest, Faculty of Physics, 3 Nano-SAE Research Centre, Bucharest, Romania

2)Petroleum-Gas University of Ploiesti, 39 Bucuresti Blv, 100680, Ploiesti, Romania


E-mail
cristina.serban@3nanosae.org


Keywords:
Ni- catalysts, urea decomposition, fuel cells, wastewater treatment, hydrogen production


Abstract:
Urea is a non-toxic, non-flammable hydrogen carrier which can be easily transported, stored and recovered from wastewater. Electro-oxidation of urea in the presence of a Ni catalyst is considered an effective approach for hydrogen production via urea decomposition. In this work, three different catalysts based on Ni (Ni/C, Ni(OH)2 and Ni/SWCNTs) were synthesized, characterized and used as catalyst incorporated in membrane electrode assembly (MEA) for urea electro-decomposition. The physico-chemical properties of catalysts were investigated by Scanning Electron Microscopy, Raman Spectroscopy, Chrono-amperommetry and Cyclic Voltammetry. Electrochemical measurements showed that Ni is promising alternative catalyst material for applications in wastewater treatment, hydrogen production and fuel cells.


Acknowledgement:
Serban Elena Cristina was supported by the strategic grant POSDRU/159/1.5/S/133652, ”In-tegrated system to improve the quality of doctoral and postdoctoral research in Romania and promotion of the role of science in society” cofinanced by the European Social Found within the Sectorial Operational Program Human Resources Development 2007 – 2013. This work was supported by a grant of the Romanian National Authority for Scientific Re-search, Program for research- Space Technology and Advanced Research - STAR, project number 15/2012 and PNCDI-II- project number 64/2011, PNCDI-II- project number 46/2014.