UNIVERSITY OF BUCHAREST
FACULTY OF PHYSICS

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Conference: Bucharest University Faculty of Physics 2016 Meeting


Section: Atmosphere and Earth Science; Environment Protection


Title:
Removal of As and Cu using magnetite nanoparticles


Authors:
Simona Liliana ICONARU (1), Cristina Liana POPA (1), Mikael MOTELICA-HEINO (2), Carmen Steluta CIOBANU (1), Daniela Predoi PREDOI (1)


Affiliation:
1)National Institute of Materials Physics, Bucuresti-Magurel, Romania,

2) ISTO UMR 7327 CNRS Université d’Orléans, France Mikael.




E-mail
dpredoi@gmail.com


Keywords:
Arsenic, Copper, Magnetite, Adsorption, Kinetics


Abstract:
The goal of this research was to use ferrous chloride tetrahydrate and ferric chloride hexahydrate (Fe2+ / Fe3+ = 0.5) as precursors in a co-precipitation method at room temperature, in a controlled atmosphere [1-2].Physical, structural and morphological characterizations of magnetite nanoparticles were performed. The obtained materials were characterized by a suite of physico-chemical techniques such as: X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR) spectroscopy, Raman spectroscopy, Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray analysis (EDAX); the determination of surface area, pore volume and pore size was achieved by Brunauer–Emmett-Teller (BET) method.This primary study delivered sufficient data to focus supplementary investigations on factors that might have an effect on the efficiency of magnetic iron oxide. The investigation methods used in this study for the complex characterization of the materials and the results presented might lead to a better understanding of the adsorption phenomena and might help to develop new materials based on magnetic iron oxide nanoparticles for various applications such as remediation of marine environment, site remediation and groundwater treatment.


References:

1.S.L. Iconaru, R. Guégan, C. L. Popa, M. Motelica-Heino, C.S. Ciobanu, D. Predoi, Magnetite (Fe3O4) nanoparticles as adsorbents for As and Cu removal, submitted Applied Clay Science.

2.D. Predoi, A study on iron oxide nanopartciles coated with dextrin obtained by coprecipitation, Digest Journal of Nanomaterials and Biostructures 2007, 2:169-173.

Acknowledgement:
These studies were partially supported by Core program PN16-480103/2016